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Phase Transition

A nonanalytic change in equilibrium behavior as control parameters vary.

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Phase Transition

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Definition

A phase transition occurs when thermodynamic properties change nonanalytically in the thermodynamic limit. First-order transitions have a discontinuity in a first derivative of a thermodynamic potential and often involve latent heat.

Order Parameters

An order parameter distinguishes phases. Magnetization in a ferromagnet and density difference in a liquid-gas transition are standard examples.

Criticality

At a continuous transition, correlation lengths can become large compared with microscopic scales. This is why very different systems can share universal critical behavior.

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