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量子力学 · 学部

Infinite Square Well

The canonical example of quantization from boundary conditions.

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Infinite Square Well

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Setup

For 0<x<a0<x<a and infinite walls at the boundaries, the wavefunction satisfies

ψ(0)=ψ(a)=0.\psi(0)=\psi(a)=0.

Solutions

The normalized stationary states are

ψn(x)=2asin(nπxa),\psi_n(x)=\sqrt{\frac{2}{a}}\sin\left(\frac{n\pi x}{a}\right),

with energies

En=n2π222ma2.E_n=\frac{n^2\pi^2\hbar^2}{2ma^2}.
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